Principles for Water Governance in a Post-COVID World: Water Sector Needs to Be Embedded in Environmental Justice

This paper argues that the crisis in humanity's relationship with water reflected in rapidly escalating demand and dangerously depleting freshwater and groundwater reserves, can be understood as the outcome of the anthropocentric assumptions underlying our current development models. These assumptions have given rise to both the challenge of severe water scarcity as well as to the kind of policies used to address it. Drawing on principles from an environmental justice framework, it calls for a drastic restructuring of the water sector on more equitable, sustainable and democratic lines. Some of the guiding principles for water governance that are suggested include ensuring that interventions in nature or river systems are along the contours of nature, focusing on managing the demand for water as against the present emphasis on supply augmentation, recognition of structural and historical inequities which determine access to water, adoption of an approach to water management that is adaptive to rapidly changing circumstances and promotion of the participation of all stakeholders in governance and knowledge production. © The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2023.

Green economy and the future in a post-pandemic World

The future to geo-political and geo-economic conundrums is by transforming current economies into inclusive and sustainable societies. In this race for global dominance and hegemony, policy makers must be wary of not forgetting institutional practices of conserving and preserving ecosystems and biospheres with pro-active and proper thinking. Governments that are in power must be sensible to realize that economies will eventually grow when more people join the formal and informal sectors, but the challenge is to have a planet that sustains our needs rather than addressing our greed. Legal systems must work harder in the 21st century to embed proper and critical thinking driven by an ecological conscience to preserve, conserve and protect the environment that sustains us. The technology that is being built and fashioned to drive businesses must submit to stringent ecological standards. With the rapid spread of Covid19, scientists are aware that humanity will be afflicted with more such zoonotic diseases primarily brought on by the global warming and climate change. Third world governments in their search for competing and contributing with the global economy forget the impending dangers of a cataclysmic warmer, hotter and unsustainable planet that will deprive burgeoning populations of food and clean water furthering a health scare. Across the globe, we have witnessed government's response to Covid19 especially in the third world and the loss of lives that could have been prevented. This affliction is bound to endure owing to the inadequate policies that fail to create low-carbon economies or submit to Sustainable Development Goals that could mitigate the debilitating effects of a globally warmer planet. In all of this, the future will be fought not over oil but wars are bound to be fought over water and food and lack of immediate or urgent healthcare support. It is observed painfully, that the people most affected or afflicted with the mostly the marginalized, the poor, the disadvantaged. In this paper, I propose how governments of the day must transform their economies to be sustainable and inclusive, ameliorate global warming, promote healthy agricultural practices, constantly set higher moral standards for a low-carbon economy and build on a healthcare system that is robust and flexible to everyone's needs. The globe after observing many discussions at Copenhagen is now becoming familiar with the reality of a resource-efficient economy and natural capital as an invaluable economic asset. © 2023 Scrivener Publishing LLC. All rights reserved.

Challenges and Solution Pathways in Water Use Through the Lens of COVID-19

Water withdrawal for public/private suppliers and public services (defined as public water use) and for irrigation (defined as irrigation water use) are essential components of agricultural water management as well as of the planning and management of domestic, commercial, and municipal water supplies. A significant fraction of the public and irrigation water use is consumptive (defined as the part of water withdrawn that is consumed) in nature, and it is primarily freshwater. Global climate change and variability have substantially impacted the large-scale drivers of freshwater resources across the globe, which include, for example, precipitation, temperature, evapotranspiration, soil moisture, and hydrologic extremes. Global environmental change has also influenced several local-scale freshwater availability drivers, such as water quality, municipal policies, and water taxation. Overall, the changes in freshwater resources have potentially stressed irrigation and public water use. Population growth has altered the supply–demand fronts of water balance, resulting in increased water supply stresses. Researchers have considered several soft-and hard-path solutions to augment the deficit in the supply–demand fronts;however, each solution has its own pros and cons. The ongoing COVID-19 pandemic has exacerbated the already existing critical issues related to sustainable future water use. New challenges have emerged, requiring both short-and long-term solutions. Hence, it is essential to understand the current public and irrigation water use changes resulting from the pandemic. An appropriate estimate of the future changes in water use would help develop/upgrade new/current water resource systems that can mitigate risks and show increased resiliency against global climate and environmental changes and unprecedented events like the COVID-19 pandemic. In this opinion chapter, we discuss some examples of the regional/local changes in water use during the ongoing pandemic and our increased preparedness or the lack of it. Additionally, the chapter focuses on the future risks and resilience of water resource systems to meet the future demands of water use as well as to face unprecedented events such as the COVID-19 pandemic. © The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer 2022.

A long‐term shift in the summer distribution of Hector's dolphins is correlated with an increase in cruise ship tourism

Before the 2020 COVID‐19 pandemic, cruise ship tourism had been one of the fastest growing segments of global tourism, presenting a range of potential impacts. At Akaroa Harbour, Aotearoa New Zealand, the number of annual cruise ship visits more than quadrupled following earthquake damage to Ōtautahi Christchurch's Lyttelton Port in 2011. Akaroa Harbour is an area of core use for endangered and endemic Hector's dolphins (Cephalorhynchus hectori). Dolphins here are exposed to some of the highest levels of cetacean tourism in Aotearoa New Zealand. Relationships were examined between growth in cruise ship visits, as well as tours focused specifically on dolphins, and long‐term trends in summer distribution of Hector's dolphins at Akaroa Harbour, from 2000 to 2020. Core use areas for Hector's dolphins within the harbour were quantified via kernel density estimation using data from 2,335 sightings from over 8,000 km of standardized survey effort. Data were allocated into four periods based on varying levels of tourism. Dolphin habitat preference varied over time, with the greatest change occurring between 2005–2011 and 2012–2015. When comparing these periods, the spatial overlap of core habitat was less than 24%. Dolphin distribution shifted towards the outer harbour after 2011 and has remained relatively consistent since. The observed shift in distribution coincided with the more than fourfold increase in annual cruise ship visits to Akaroa Harbour. Several pressures related to cruise ship tourism are likely to have influenced habitat preferences of dolphins. Further investigation into causal factors of the observed shift is warranted. In the wake of the COVID‐19 pandemic, the future of cruise ship and wildlife tourism is in flux. Our findings suggest that the future re‐development of this industry should follow a precautionary approach, with the onus on industry to provide evidence of sustainability before proceeding.

COVID-19 Waste as Source of Microplastics in the Environment: Implication for Aquatic Species, Human, and Remediation Measures- A Review

Coronavirus (COVID-19) pandemic ushered in a new era that led to the adjustments of diverse ecosystems. The pandemic restructured the global socio-economic events which prompted several adaptation measures as a response mechanism to cushion the negative impact of the disease pandemic. Critical health safety actions were impera-tive to curtail the spread of the disease such as wearing personal protective equipment (PPEs), masks, goggles, and using sanitizers for disinfection purposes. The daily de-mands for the products by individuals and medical personnel heightened their pro-duction and consumption, leading to a corresponding increase of COVID-19 wastes in the environment following indiscriminate waste disposal and poor waste management. The persistent occurrence of COVID-19 wastes aggravated microplastics (MPs) con-tamination in the aquatic ecosystem following the breakdown of PPEs-based plastics via oxidation, fragmentation, and photo-degradation actions. These MPs are transport-ed in the aquatic environment via surface runoff and wind action, apart from discrete sources. MPs' presence in the aquatic systems is not without repercussions. Ingestion of MPs by aquatic organisms can cause several diseases (e.g., poor growth, oxidative distress, neurotoxicity, developmental toxicity, reproductive toxicity, immunotoxicity, and organ toxicity). Humans are at high risk of MPs uptake. Apart from aerial and soil contamination sources, consumption of aquatic food products is a critical pathway of MPs into the human body. MP toxicities in humans include liver disorder, respiratory failure, infertility, hormonal imbalance, diarrhea, developmental disorder, and mortal-ity. Measures to alleviate the effect of COVID-19 waste litters include effective waste management plans and the adoption of technologies to extract cum degrade MPs from the aquatic and terrestrial environment.

Impacts of COVID-19 on small-scale freshwater carp and coastal brackish water shrimp farming in India

The present study was simultaneously conducted in two distantly located areas to assess the impacts of COVID-19 on farming processes, instantaneous financial impacts and mitigation strategies adopted by the farmers in the small scale freshwater carp farming and coastal brackish water shrimp farming sectors in India. Primary data were collected through interview of the farmers with the help of pre-tested structured interview schedules. Though the initial impact in both the sectors were substantial, freshwater carp farmers mitigated the crises comparatively well because of wider option in alternative livelihood, low cost locally available inputs, mobilization of local market, direct door to door vending of live fish and mobilization of women work force from the family in the farming sector. Untapped resource in the form of women's' participation in the freshwater farming practices was noteworthy during the pandemic period which increased polynomially (y = - 1.0714x2 + 7.5286x -2.2;R2 = 0.9648). As the shrimp farming sector was dependent upon external markets and burdened with high cost inputs primarily supplied by the input dealers on credit basis, the sector has to bear the burden most. Garret's Rank analysis revealed that integration with other production sectors ranked first as mitigation perception to the freshwater carp farmers, whereas, to the coastal shrimp farmers, the highest rank was with the perception that everything will be normalized within 2- 3 months naturally. Garret's Rank analysis also revealed that in both the sectors, the farmers most important need was credit from the Govt. source in mitigating COVID-19 like crisis in future. © D. Hait.

Quantification and characterization of macro- and mesoplastic items in the water column of the river Waal.

Although studies on plastic concentrations mainly focus on the marine environment, recently, an increasing number of studies point out environmental consequences in freshwater environments around the world. However, there still is a paucity of field data on the abundance of riverine plastic items, in particular in the water column. In this study, we provide an overview of macro- and mesoplastic concentrations, categories, ages, and origin over several years in the water column of the river Waal, in the Netherlands. The river water column was passively sampled at two selected locations using a stow net at very low and low discharges (range 537 - 1345 m3.s-1). The most dominant macro- and mesoplastic categories were 'Miscellaneous plastic waste', including "Plastic film 2.5 - 50 cm (soft)" and "Plastic film 0 - 2.5 cm (soft)" as main categories. Macro- and mesoplastic categories were found to show limited variability during several years of monitoring. The mean macroplastic concentration (± SD) ranged between 2.2 × 10-3 ± 0.001 and 7.4 × 10-3 ± 0.003 particles.m-3 for October 2020 and November 2018, respectively. In 2020, the plastic concentrations showed a sharp decrease compared to the previous years, most likely as a consequence of the COVID-19 crisis. The origin of the plastics (e.g., countries) also showed little variability during monitoring. The consistency of several characteristics of the collected plastic suggests that the same sources were responsible for the macro- and mesoplastic input into the river Waal during low discharges and over multiple years. We present the first temporal assessment of macro- and mesoplastic concentrations and composition in the water column of the river Waal. The outcome of the current study can be used to support the development of management measures by decision makers.

Direct and Indirect Impacts of Disposable Face Masks and Gloves on Freshwater Benthic Fauna and Sediment Biogeochemistry

To reduce virus transmission, the use of personal protective equipment (PPE) increased substantially during the COVID-19 global pandemic. As a result, disposable face masks and gloves made from plastic polymers rapidly entered the environment, with little understanding of ecological impacts. Many plastic polymers sink to the bottom of freshwater bodies, either immediately or following biofouling and degradation, posing a potential risk to the benthos. We assessed the acute and chronic ecotoxicity of disposable polypropylene face masks and nitrile gloves on Lumbriculus variegatus, a benthic ecosystem engineer. In microcosm experiments, we also investigated direct impacts on sediment biogeochemistry and indirect impacts mediated by toxicity to L. variegatus. Exposure to fragments of both masks and gloves decreased vitality of L. variegatus. Gloves were acutely toxic, but mask toxicity was mediated by physical interactions. Glove fragments significantly decreased nitrogen removal and phosphorus release to the water column. Both materials suppressed the ecosystem engineering role of L. variegatus by decreasing its impact on microalgal primary production, net ecosystem metabolism, and sediment nitrate consumption. The influx of PPE to the environment may have profound and cascading negative impacts on benthic organisms and ecosystem function, suggesting the need for improved management of PPE litter. © 2022 American Chemical Society.

Risk preference, risk perception, and purchase recovery period: Empirical evidence from salmon contamination of COVID-19 in China

This paper investigates the recovery period of consumer salmon purchase intention after food scares at the Xinfadi wholesale market in China during the COVID-19 pandemic and examines the impact mechanism of risk preference and risk perception on the period duration. Our empirical analysis is based on a survey of 655 salmon consumers in Beijing, Tianjin, and Shanghai. We estimate that the purchase intention recovery period lasts 21 weeks among the surveyed consumers after the shock. Although the epidemic risk levels of the three cities are different, there is a significant difference only in the recovery period from 5 to 7th weeks. The Cox proportional hazards model results further show that consumers with less risk-averse are more active in resuming purchase intention, and the effect of risk perception is just the opposite. Moreover, risk perception has a moderating effect on risk preference and recovery period. Finally, we put forward three possible policy implications: attaching nucleic acid detection certificate, strengthening cold chain management, and diversifying cooking methods.

COVID-19 and Water Variables: Review and Scientometric Analysis.

COVID-19 has changed the world since 2020, and the field of water specifically, boosting scientific productivity (in terms of published articles). This paper focuses on the influence of COVID-19 on scientific productivity with respect to four water variables: (i) wastewater, (ii) renewable water resources, (iii) freshwater withdrawal, and (iv) access to improved and safe drinking water. The field's literature was firstly reviewed, and then the maps were built, emphasizing the strong connections between COVID-19 and water-related variables. A total of 94 countries with publications that assess COVID-19 vs. water were considered and evaluated for how they clustered. The final step of the research shows that, on average, scientific productivity on the water topic was mostly conducted in countries with lower COVID-19 infection rates but higher development levels as represented by gross domestic product (GDP) per capita and the human development index (HDI). According to the statistical analysis, the water-related variables are highly significant, with positive coefficients. This validates that countries with higher water-related values conducted more research on the relationship with COVID-19. Wastewater and freshwater withdrawal had the highest impact on the scientific productivity with respect to COVID-19. Access to safe drinking water becomes insignificant in the presence of the development parameters.

Multigenerational effects of microplastic fragments derived from polyethylene terephthalate bottles on duckweed Lemna minor: Size-dependent effects of microplastics on photosynthesis.

The 2019 global coronavirus disease pandemic has led to an increase in the demand for polyethylene terephthalate (PET) packaging. Although PET is one of the most recycled plastics, it is likely to enter the aquatic ecosystem. To date, the chronic effects of PET microplastics (MPs) on aquatic plants have not been fully understood. Therefore, this study aimed to investigate the adverse effects of PET MP fragments derived from PET bottles on the aquatic duckweed plant Lemna minor through a multigenerational study. We conducted acute (3-day exposure) and multigenerational (10 generations from P0 to F9) tests using different-sized PET fragments (PET0-200, < 200 µm; PET200-300, 200-300 µm; and PET300-500, 300-500 µm). Different parameters, including frond number, growth rate based on the frond area, total root length, longest root length, and photosynthesis, were evaluated. The acute test revealed that photosynthesis in L. minor was negatively affected by exposure to small-sized PET fragments (PET0-200). In contrast, the results of the multigenerational test revealed that large-sized PET fragments (PET300-500) showed substantial negative effects on both the growth and photosynthetic activity of L. minor. Continuous exposure to PET MPs for 10 generations caused disturbances in chloroplast distribution and inhibition of plant photosynthetic activity and growth. The findings of this study may serve as a basis for future research on the generational effects of MPs from various PET products.

Occurrence, effects, and ecological risks of chemicals in sanitizers and disinfectants: A review

In response to the novel coronavirus referred to as severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) – a virus that causes COVID-19 disease has led to wide use of sanitizers and disinfectants. This, in turn, triggered concerns on their potential deleterious effects to human health and the environment due to numerous chemicals incorporated in both product categories. Here, the current state of science regarding the occurrence and ecological effects of different classes of chemicals in these products (e.g., ultraviolent filters, fragrances, etc.) are summarized in different natural (e.g., rivers) and engineered (e.g., wastewater treatment plants) systems. Data collected in the literature suggests chemicals incorporated in sanitizers and disinfectants are present in the environment, and a large portion are toxic to fish, algae, and daphnia. Using the risk quotient approach based on occurrence data, we found eight chemicals that posed the highest risk to aquatic organisms in freshwater systems were benzalkonium chloride, 4-chloro-m-cresol, sodium ortho phenyl phenate, hydrogen peroxide, 1, 2-propanediol, 4-Methyl-benzilidine-camphor, ethylhexyl methoxy cinnamate, and octocrylene. Considering limited occurrence and effects information for most chemicals, further studies on environmental monitoring and potential consequences of long-term exposure in aquatic ecosystems are recommended.

Release of microplastics from disposable face mask in tropical climate.

Outbreak of COVID 19 has caused an abrupt surge in the consumption of disposable face masks around the world. WHO has stated that wearing a face mask in public reduces the chances of being exposed to COVID 19 virus. With unchecked disposal of these used masks, a new kind of pollutant has emerged in the environment. Since these masks are generally made of polypropylene and polyurethane material, they can be considered as a potential source of microplastics (MPs) in the environment. In this study, we have evaluated the release of MPs particles from these face masks (namely from N95 and surgical masks) in deionized (DI) water and tap water over the span of 1 to 180 days. More specifically, a systematic study has been carried out to see the effect of temperature on release of MPs in water. MPs particles released in tap water (837 ± 113 particles/piece in 30 days) were significantly higher than that in DI water (564 ± 37 particles/piece in 30 days). When these masks were kept at a constant temperature of 45 °C for 30 Days, highest amount of MPs release (N95 899 ± 65 particles, Surgical 1038 ± 65 particles/piece) was observed as compared to other conditions. Most of the MPs particles released were polypropylene which were transparent and white in case of N95 while for surgical mask they were found to be of blue and white colour. With the aging of masks in water, quantity of MPs release was increased with simultaneous reduction in their size. Our study indicates that these disposable face masks are emerging to be a prominent source of MPs release in the environment and more hazardous for the tropical climate.

Direct and Indirect Impacts of Disposable Face Masks and Gloves on Freshwater Benthic Fauna and Sediment Biogeochemistry

To reduce virus transmission, the use of personal protective equipment (PPE) increased substantially during the COVID-19 global pandemic. As a result, disposable face masks and gloves made from plastic polymers rapidly entered the environment, with little understanding of ecological impacts. Many plastic polymers sink to the bottom of freshwater bodies, either immediately or following biofouling and degradation, posing a potential risk to the benthos. We assessed the acute and chronic ecotoxicity of disposable polypropylene face masks and nitrile gloves on Lumbriculus variegatus, a benthic ecosystem engineer. In microcosm experiments, we also investigated direct impacts on sediment biogeochemistry and indirect impacts mediated by toxicity to L. variegatus. Exposure to fragments of both masks and gloves decreased vitality of L. variegatus. Gloves were acutely toxic, but mask toxicity was mediated by physical interactions. Glove fragments significantly decreased nitrogen removal and phosphorus release to the water column. Both materials suppressed the ecosystem engineering role of L. variegatus by decreasing its impact on microalgal primary production, net ecosystem metabolism, and sediment nitrate consumption. The influx of PPE to the environment may have profound and cascading negative impacts on benthic organisms and ecosystem function, suggesting the need for improved management of PPE litter.

Freshwater Mussels Show Elevated Viral Richness and Intensity during a Mortality Event.

Freshwater mussels (Unionida) are among the world's most imperiled taxa, but the relationship between freshwater mussel mortality events and infectious disease is largely unstudied. We surveyed viromes of a widespread and abundant species (mucket, Actinonaias ligamentina; syn: Ortmanniana ligamentina) experiencing a mortality event of unknown etiology in the Huron River, Michigan, in 2019-2020 and compared them to viromes from mucket in a healthy population in the St. Croix River, Wisconsin and a population from the Clinch River, Virginia and Tennessee, where a mortality event was affecting the congeneric pheasantshell (Actinonaias pectorosa; syn: Ortmanniana pectorosa) population. We identified 38 viruses, most of which were associated with mussels collected during the Huron River mortality event. Viral richness and cumulative viral read depths were significantly higher in moribund mussels from the Huron River than in healthy controls from each of the three populations. Our results demonstrate significant increases in the number and intensity of viral infections for freshwater mussels experiencing mortality events, whereas individuals from healthy populations have a substantially reduced virome comprising a limited number of species at low viral read depths.

Ornamental fish export during the Covid-19 pandemic

Indonesia is one of the top 10 exporters of ornamental fish in the world. However, at the beginning of the Covid-19 pandemic, the performance of Indonesia's export of ornamental fish experienced significant contractions. The purposes of this paper were (1) to find groups of ornamental fish product types that experienced an increase and decrease in export value during the Covid-19 pandemic;(2) to find changes in the export share of ornamental fish by province of origin and airport/port of loading during the COVID-19 pandemic;(3) to determine the level of market penetration of Indonesian ornamental fish products in the international market;(4) to determine the strategy for increasing the export value of ornamental fish products. The group of marine ornamental fish product types during the Covid-19 pandemic experienced a greater decline in export value than the freshwater ornamental fish group. The share of ornamental fish export value from the Soekarno-Hatta Airport reached 96.17% of the total ornamental fish export value in the first quarter of 2021. The Indonesian ornamental fish market penetration index in 2019 reached 0.54. This means that Indonesia still has a large opportunity to increase the ornamental fish market in the international market. © 2022, BIOFLUX SRL. All rights reserved.

Toxicity assessment of SARS-CoV-2-derived peptides in combination with a mix of pollutants on zebrafish adults: A perspective study of behavioral, biometric, mutagenic, and biochemical toxicity.

The dispersion of SARS-CoV-2 in aquatic environments via the discharge of domestic and hospital sewage has been confirmed in different locations. Thus, we aimed to evaluate the possible impacts of zebrafish (Danio rerio) exposure to SARS-CoV-2 peptide fragments (PSPD-2001, 2002, and 2003) alone and combined with a mix of emerging pollutants. Our data did not reveal the induction of behavioral, biometric, or mutagenic changes. But we noticed an organ-dependent biochemical response. While nitric oxide and malondialdehyde production in the brain, gills, and muscle did not differ between groups, superoxide dismutase activity was reduced in the "PSPD", "Mix", and "Mix+PSPD" groups. An increase in catalase activity and a reduction in DPPH radical scavenging activity were observed in the brains of animals exposed to the treatments. However, the "Mix+PSPD" group had a higher IBRv2 value, with NO levels (brain), the reduction of acetylcholinesterase activity (muscles), and the DPPH radical scavenging activity (brain and muscles), the most discriminant factors for this group. The principal component analysis (PCA) and hierarchical clustering analysis indicated a clear separation of the "Mix+PSPD" group from the others. Thus, we conclude that exposure to viral fragments, associated with the mix of pollutants, induced more significant toxicity in zebrafish adults than in others.

Impact of climate-driven temperature increase on inland aquaculture: Application to land-based production of common carp (Cyprinus carpio L.).

Climate change will expose the food-producing sector to a range of challenges. Inland aquaculture farms are particularly vulnerable, due to the difficulty in changing their location, and therefore require specific tools to predict the influence of direct and indirect effects on production, environment and economic feasibility. The objective of our study was to apply a simple set of models to produce a set of growth, risk and suitability maps for stakeholders within the common carp sector in Poland, to assist decision-making under two different scenarios of climate change: a moderate situation (RCP 4.5) and an extreme situation (RCP 8.5). We used present (2000-2019) and future projections (2080-2099) for water surface temperature based on land surface temperature data from regionally downscaled climate models to draw maps to: (i) show optimal temperature conditions for carp growth, (ii) assess risk of disease outbreak caused by three important common carp pathogens: Cyprinid herpesvirus 3 (CyHV-3), carp oedema virus (CEV) and spring viremia of carp (SVCV) and (iii) predict potential suitability changes of carp farming in Poland. The study identified areas with the most and least favourable temperature conditions for carp growth, as well as those areas with the highest/lowest number of days with suitable temperatures for virus infection. These suitability maps showed the combined effect of direct and indirect effects of climate change projections under RCP 8.5 and RCP 4.5 scenarios. The approach applied herein will be of use worldwide for analysing the risks of temperature increase to land-based aquaculture, and the results presented are important for carp farmers in Poland and elsewhere, industry in general, and government stakeholders, to understand the direct and indirect effects of climate change on the triple bottom line of people, planet, and profit.

Environmental and ecotoxicological effects of drugs used for the treatment of COVID 19

Consumption of different pharmaceuticals has increased since the COVID-19 pandemic. Some health institutions worldwide approved the use of drugs such as ivermectin, hydroxychloroquine, azithromycin, dexamethasone, favipiravir, remdesivir, lopinavir-ritonavir, chloroquine, dexamethasone for the treatment of the virus. Once consumed by humans, these compounds are released in urine and faeces, ending up in wastewater and conducted to treatment plants or directly discharged without prior treatment into surface water and soil, with minimum values recorded between 7 ng/L and < 0.08 mu g/L for azithromycin and ivermectin respectively, as well as dexamethasone with 0.73 ng/L in surface water and an average of 50-60 ng/L for favipiravir. Their presence has numerous toxicological effects on aquatic and terrestrial species, influencing population decline and altering the growth of organisms. However, the environmental consequences of pharmaceuticals in the environment are poorly known, especially for antivirals studied in this article. This work aims to analyze the presence, treatment and ecotoxicity of drugs used in the pandemic COVID 19, mainly focusing on aquatic and terrestrial ecosystems since that is where they arrive through wastewater. Ecotoxicological effects on flora, fauna and humans are also analyzed. Once there, they persist in the environment causing severe ecological damage, developmental and growth disorders in animals and plants and, in many cases, even the death of species.

Ecotoxicity of Heteroaggregates of Polystyrene Nanospheres in Chironomidae and Amphibian.

Due to their various properties as polymeric materials, plastics have been produced, used and ultimately discharged into the environment. Although some studies have shown their negative impacts on the marine environment, the effects of plastics on freshwater organisms are still poorly studied, while they could be widely in contact with this pollution. The current work aimed to better elucidate the impact and the toxicity mechanisms of two kinds of commercial functionalized nanoplastics, i.e., carboxylated polystyrene microspheres of, respectively, 350 and 50 nm (PS350 and PS50), and heteroaggregated PS50 with humic acid with an apparent size of 350 nm (PSHA), all used at environmental concentrations (0.1 to 100 µg L-1). For this purpose, two relevant biological and aquatic models-amphibian larvae, Xenopus laevis, and dipters, Chironomus riparius-were used under normalized exposure conditions. The acute, chronic, and genetic toxicity parameters were examined and discussed with regard to the fundamental characterization in media exposures and, especially, the aggregation state of the nanoplastics. The size of PS350 and PSHA remained similar in the Xenopus and Chironomus exposure media. Inversely, PS50 aggregated in both exposition media and finally appeared to be micrometric during the exposition tests. Interestingly, this work highlighted that PS350 has no significant effect on the tested species, while PS50 is the most prone to alter the growth of Xenopus but not of Chironomus. Finally, PSHA induced a significant genotoxicity in Xenopus.